Question 8

Learners are given the following two unknown half-cells:

Half-cell 1: Q2+ (aq) | Q(s)

Half-cell 2: Pt | R2(g) | R(aq)

During an investigation to identify the two half-cells, the learners connect each half-cell alternately to a Cd2+(aq) | Cd(s) half-cell under standard conditions. For each combination of two half-cells, they write down the net cell reaction and measure the cell potential.

The results obtained for the two half-cell combinations are given in the table below.

8.1 Write down THREE conditions needed for these cells to function as standard cells. (3)

8.2 For Combination I, identify:

8.2.1 The anode of the cell (1)

8.2.2 Q by using a calculation (5)

8.3 For Combination II, write down the:

8.3.1 Oxidation half-reaction (2)

8.3.2 NAME or FORMULA of the metal used in the cathode compartment (1)

8.4 Arrange the following species in order of INCREASING oxidising ability:

Q2+ ; R2 ; Cd2+

Explain fully how you arrived at the answer. A calculation is NOT required. (4)

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